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评论来自 ldene

Spawning in the Dread Wastes, yielding 5-7 ore.

评论来自 Mookosh

Gems can only drop from these and other veins in Pandaria if you possess 古代熊猫人矿镐
But even with the pick, the drop rate is abysmally low.

评论来自 GoHF

As of 5.3 (PTR), these can now be mined from skill level 1, yielding 凯帕琥珀裂片.

评论来自 Eido

Note to those with 珠宝加工 who are searching for some information as I was about obtaining rare, MoP gems:

When 选矿, the best ore to receive rare, Mist of Pandaria gems is either 黑色延极矿石 OR 白色延极矿石, with an average, gem, drop rate of 17% each (according to Wowhead).

This ore can be obtained directly via two methods:

These can be mined from two, rare-node-spawns: 延极矿脉 or 富延极矿脉.
If you are Revered with 阡陌客, plant 毒蛇茎种子 for random chances at obtaining either type of Trillium Ore per plant.

This ore can be obtained indirectly by executing two steps:

If you are Revered with 阡陌客, plant 欢歌铃种子 to farm 祥和微粒 (yields 1 Mote per plant) and eventually make 祥和之灵 to use as currency in the next step.
Purchase a stack of 5 Trillium Ore in exchange for 1 祥和之灵.

Here is a quick list of each rare gem for easy-viewing:
源红石
朱砂玛瑙
日曜石
荒玉
河心石
皇紫晶

Since Trillium nodes are rare spawns, a more surefire way to obtain rare, MoP gems is through 炼金术, specifically through Transmutations.
Being a 转化大师 will result in the highest transmutation yields. Here is a quick list of each transmutation recipe for easy-viewing.

NOTE: Each recipe requires a 黄金莲 and the Uncommon version (listed below) of each, rare gem.

虎纹石
青金石
日长石
劣生石
潘达利亚榴石
紫翠玉

转化：源红石
转化：皇紫晶
转化：日曜石
转化：朱砂玛瑙
转化：河心石
转化：荒玉

If you DO decide to transmute and you are hard-up for 黄金莲, you can:

A) buy 2 in exchange for 1 祥和之灵 from NPCS:
达奇 (horde)
克里斯托 (alliance)

B) become Revered with 阡陌客 to purchase, then plant:
谜之种 to get a rare chance at gathering a Golden Lotus
欢歌铃种子 to farm 祥和微粒 (yields 1 Mote per plant) and eventually make 祥和之灵 to use as currency in option "A".

LASTLY,

The least-effective way to farm rare, MoP gems is through prospecting:
凯帕琥珀 OR 幽冥铁矿石
Each having roughly a 5% rare-gem, drop rate (according to Wowhead).

I hope this was helpful and saved you some time! Please feel free to add or suggest anything else!

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富凯帕琥珀矿脉

此物品存在于恐惧废土（124），螳螂高原（112），和围攻砮皂寺（7）.

指南

Mining Guide Mists of Pandaria: Gathering Profession Overview

富凯帕琥珀矿脉

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